The Bohr – deBroglie Connection

 

According to Bohr theory and deBroglie’s matter wave notion, how fast is an electron traveling around the nucleus when it is in the n=1 energy level? What is the electron’s kinetic energy?

 

The circumference, C,  is 2pR

C = 2pR = 2px5.3x10-11 m

Where R is from the Bohr radius for n=1

C = 3.33x10-10 m


To be in phase, the wave must make an integral number of complete cycles around the path. For the first energy level, 1 complete cycle must be completed around the circumference of the n=1 path.

  or

 

E= ˝ mv2 = ˝ x 9.11x10-31kg x (2.18x10-6)2 = 2.17x10-18 J 

 

This answer matches the energy of the n=1 very closely from the equation:

 

*  

 

To test this we can see if the physical forces are balanced, that is:

centripetal force = force of attraction.

 

Fcentripetal=mv2/R = Fattraction= kq2/R2

 

Where k is the electric field constant 9x109 Nm2/C2 and q is the charge on both an electron and a proton, 1.6x10-19C.

 

Fcentripetal=mv2/R =9.11x10-31 kg x (2.18x106 m/s)2/5.3x10-11 m = 8.2x10-8 Newtons

 

Fattraction= kq2/R2 = 9x109 Nm2/C2x(1.6x10-19C)2/(5.3x10-11)2 m =8.2x10-8 Newtons

 

Perfect! This should also work quite nicely for all hydrogen-like ions, He+1, Li+2, …